FLUXES IN FIRE ASSAY
Fire Assay SL can supply all the necessary fluxes for the fire assay process, and we can also pre-mix them according to your own recipe. Externalising the production of your fluxes not only saves you time, but also avoids handling hazardous chemicals in your laboratory.
A flux is something which converts compounds infusible at a certain temperature into others which melt at this temperature.
In general terms, in order to fuse an acid subtance, it is necessary to employ a basic flux such as litharge or sodium carbonate.
On the other hand if we want to fuse a basic substance, we will use an acid flux such as silica or borax.
A desulphurizing agent is a substance which has a strong affinity for sulphur and which is therefore capable of separating it from some of its compounds.
Assay grade Litharge (PbO) is the key ingredient of assay flux. During the reductive fusion that takes place in the fire assay crucible, Litharge has the following functions:
- Collector: When Litharge reduces into lead, it rains downd under the form of droplets through the sample collecting all metals
- Fluxing agent
- Desulphuriser: Prevents the formation of ‘Matte’ (by oxidation of sulphurs)
- Solvent: Litharge acts as a solvent for metallic oxides
- Prevents formation of ‘Speiss‘ (by oxidation of antimony and arsenic).
- Prevents reduction into lead button of those metals below lead in the redox potential series.
- Combined with acid reagents PbO forms an efficient Solventf or acid and basic Oxide Compounds that are too viscous at furnace temperature.
|%||< 0.0015||< 0.0010||< 0.0250||< 0.0020||< 0.0010||< 0.0010|
ASSAY ANHYDROUS SODIUM CARBONATE
Sodium Carbonate (Na2CO3) or soda ash is a powerful basic assay flux and one of the cheapest available for assay purposes:
- As it easily forms sulphates and sulphides, it helps desulphurizing the sample (helps preventing the apparition of Matte) .
- The other reason for using sodium carbonate, is that it has fluxing effects. Indeed, it contributes to reduce the melting temperature of the mixture by forming eutectics.
We recommend using dense sodium carbonate because it absorbs very little atmospheric moisture, and therefore has a longer shelf live.
ASSAY ANHYDROUS POTASSIUM CARBONATE
|K2CO3||Na2CO3||KCl||Fe||Moisture||Heavy metals (Pb)||K2SO4||Particle size > 270 mesh|
Potassium Carbonate (K2CO3) is also a basic assay flux very similar to sodium carbonate, but is has the disadvantage of being more expensive.
However, adding small quantities of Potassium carbonate is interesting because it will contribute to reduce the melting temperature of the mixture in the fire assay crucible.
Indeed, a mixture of sodium and potassium carbonate melts at a lower temperature than either one alone, and for this reason the mixture is used whenever it is desired to maintain a low temperature during the assay. The lead assay is an example and in fact is now about the only case in which it is still customary to use potassium carbonate in fire assaying.
ASSAY ANHYDROUS BORAX
Borax (Na2B407) is almost always present in all Fire Assay fluxes because it greatly reduces the fusing point of all slags, and it is also an excellent solvent for metallic oxides.
At red heat anhydrous borax becomes a strong acid and practically dissolves all metallic oxides and fluxes, both acid and basic.
If too much borax is used in the assay of siliceous ores there results a very tough, glassy or stony slag which holds tenaciously to the lead button. This is probably due partly to the effect of borax in reducing the coefficient of expansion of the slag and partly to its action in preventing crystallization. When the attempt is made to separate the lead and slag, a film of lead will often adhere to the slag and give the assayer much trouble. The remedy for this condition is, first, to reduce the quantity of borax used and then, if necessary, to increase the bases.
|B2O3||Equivalent Na2B4O7||Na2O||H2O||SO4||Fe||Particle size|
ASSAY ANYDROUS POTASSIUM NITRATE
Commonly known as niter, this fire assay flux is a powerful oxidizing agent.
It melts at 339ºC and fuses at a low temperature without alteration, but at a higher temperature it breaks up, giving off oxygen, which oxidizes sulphur and many of the metals, notably lead and copper.
It is used in the fire assay especially to oxidize sulphides, arsenides, antimonides, etc.
Many assayers object to its use because of the oxidizing effect on silver. Large amounts of potassium nitrate or sodium nitrate cause boiling of the crucible charge and necessitate careful heating to prevent loss.
ASSAY ANHYDROUS SODIUM NITRATE
Sodium nitrate behaviour is very similar to the one of potassium nitrate. However sodium nitrate is cheaper.
Silica (SiO2) is the strongest available acid reagent. it combines with the metal oxides to form silicates which are the foundation of almost all slags.
It is also very useful to protect the crucibles and scorifiers from the corrosive action of Litharge. However , the addition of too much silica will cause the loss of precious metals by the formation of slags or of Matte.
Finally, silica also helps reducing the melting point of the mixture because it forms eutectics.